Resin composition for encapsulating semiconductor chip and semiconductor device therewith

ABSTRACT

An epoxy resin composition for encapsulating a semiconductor chip, which has good flowability without deterioration in curability. Specifically, a resin composition is disclosed for encapsulating a semiconductor chip containing a phenol aralkyl type epoxy resin containing biphenylene structure(A), a phenol aralkyl type resin containing phenylene or biphenylene structure (B), an inorganic filler (C) and a curing accelerator (D) as main components, further containing a silane coupling agent (E) in 0.01 wt % to 1 wt % both inclusive of the total amount of the epoxy resin composition and a Compound (F) containing two hydroxyl groups combined with each of adjacent carbon atoms on a naphthalene ring in more than or equal to 0.01 wt % of the total amount of the epoxy resin composition.

This application is a continuation-in-part of our U.S. patent application Ser. No. 10/797,706 filed Mar. 10, 2004, which is now U.S. Pat. No. 7,023,098 and is based on Japanese patent application No. 2003-083637 and Japanese patent application No. 2003-083938, the content of which is incorporated hereinto by reference.

BACKGROUND OF THE INVENTION

1. Field of the Invention

This invention relates to a resin composition for encapsulating a semiconductor chip and a semiconductor device therewith.

2. Description of the Related Art

Recently, epoxy resin compositions have been predominantly used for encapsulating a semiconductor chip because of their good balance among productivity, a cost and reliability. Along with reduction in a size and a thickness in a semiconductor device, an epoxy resin composition for encapsulating with a lower viscosity and higher strength has been needed. Furthermore, in terms of environmental concerns, it has been increasingly needed to make a device fire-resistant without a fire retardant such as Br compounds and antimony oxide. From such a situation, there has been recently a distinctive tendency to employing a less viscous resin and adding more inorganic fillers to an epoxy resin composition.

As a new trend, a semiconductor device has been more frequently mounted using an unleaded solder with a higher melting point than a conventional solder. For applying such a solder, a mounting temperature must be higher by about 20° C. than a conventional temperature, and thus a mounted semiconductor device becomes considerably less reliable than a device of the related art. Therefore, the need for improving reliability in a semiconductor device by providing a higher-level epoxy resin composition has increasingly become stronger, which further accelerates reducing a resin viscosity and increasing the amounts of inorganic fillers.

As well-known technique, a low viscosity and a high flowability during molding can be maintained by using a resin with a lower melt viscosity (see, Japanese Patent Application NO. 1995-130919 (pp. 2-5)) or by surface-processing inorganic fillers with a silane coupling agent for increasing the amounts of the inorganic fillers (see, Japanese Patent Application NO. 1996-20673 (pp. 2-4)).

However, any of these methods cannot simultaneously meet all requirements of crack resistance, higher flowability and fire resistance. Thus, there has been needed technique in which a resin with improved crack and fire resistance can be used and the amounts of inorganic fillers can be increased to sufficiently improve reliability without deterioration in flowability or curing property.

SUMMARY OF THE INVENTION

In view of the situation, an objective of this invention is to provide technique whereby flowability can be improved without deterioration in curability in a resin composition for encapsulating a semiconductor chip during molding.

This invention provides a resin composition for encapsulating a semiconductor chip comprising: an epoxy resin (A) represented by general formula (1):

wherein R represents hydrogen or alkyl having up to four carbon atoms; and n is a positive number from 1 to 10 as an average; a phenol resin (B) represented by general formula (2):

wherein R₁ represents phenylene or biphenylene; R₂ represents hydrogen or alkyl having up to four carbon atoms; and n is a positive number from 1 to 10 as an average; an inorganic filler (C); a curing accelerator (D); a silane coupling agent (E); and Compound (F) containing two and more hydroxyl groups on adjacent carbon atoms comprising an aromatic ring.

The resin composition for encapsulating a semiconductor chip of this invention comprises the epoxy resin represented by general formula (1) and the phenol resin represented by general formula (2), and further comprises Compound (F) as an essential component, so that sufficient curability and flowability can be ensured.

The resin composition for encapsulating a semiconductor chip of this invention may contain the epoxy resin (A), the phenol resin (B), the inorganic filler (C) and the curing accelerator (D) as main components.

The resin composition for encapsulating a semiconductor chip of this invention may comprise the compound (F) in more than or equal to 0.01 wt %, which may further improve flowability without deterioration in curability during molding.

The resin composition for encapsulating a semiconductor chip of this invention may comprise the silane coupling agent (E) in 0.01 wt % to 1 wt % both inclusive, which may further improve curability and flowability during molding.

The resin composition for encapsulating a semiconductor chip of this invention may comprise an inorganic filler (C) in 84 wt % to 90 wt % both inclusive, ensuring that the resin composition can be less viscous and stronger.

In the resin composition for encapsulating a semiconductor chip of this invention, the compound (F) may contain two hydroxyl groups combined with each of adjacent carbon atoms comprising the aromatic ring, which may allow curability and flowability to be suitably ensured during molding.

In the resin composition for encapsulating a semiconductor chip of this invention, the aromatic ring may be a naphthalene ring, which may further improve curability and flowability during molding.

In the resin composition for encapsulating a semiconductor chip of this invention, the compound (F) may contain two hydroxyl groups combined with each of adjacent carbon atoms comprising the naphthalene ring, which may further improve balance between curability and flowability during molding.

This invention also provides a semiconductor device wherein a semiconductor chip is encapsulated by the use of the resin composition for encapsulating a semiconductor chip described above. Since the semiconductor device according to this invention is encapsulated by the resin composition for encapsulating a semiconductor chip, production stability can be adequately secured.

As described above, this invention can provide a resin composition for encapsulating a semiconductor chip having good flowability during molding while maintaining curability by using an epoxy resin composition comprising a compound containing two and more hydroxyl groups combined with each of adjacent carbon atoms comprising an aromatic ring.

BRIEF DESCRIPTION OF THE DRAWINGS

The above and the objectives, features and advantages of this invention will become apparent with reference to the following preferred embodiments and the accompanying drawing.

FIG. 1 is a cross-sectional view showing a structural example of a semiconductor device according to an embodiment of this invention.

DETAILED DESCRIPTION OF THE INVENTION

A resin composition according to this invention comprises an epoxy resin (A) represented by general formula (1):

wherein R represents hydrogen or alkyl having up to four carbon atoms; and n is a positive number from 1 to 10 as an average,

a phenol resin (B) represented by general formula (2):

wherein R₁ represents phenylene or biphenylene; R₂ represents alkyl having up to four carbon atoms; and n is a positive number from 1 to 10 as an average,

an inorganic filler (C),

a curing accelerator (D),

a silane coupling agent (E) and

Compound (F) containing two and more hydroxyl groups combined with each of adjacent carbon atoms comprising an aromatic ring, as essential components.

An epoxy resin composition of the present invention can contain each component as follows:

-   (A): 1 to 40% weight. -   (B): 1 to 40% weight. -   (C): 40 to 97% weight. -   (D): 0.001 to 5% weight. -   (E): 0.01 to 1% weight. -   (F): 0.01 to 1% weight.     There will be described each component constituting the epoxy resin     component for encapsulating a semiconductor chip according to this     invention.

The epoxy resin represented by general formula (1) has a hydrophobic and rigid biphenylene structure within a main chain thereof. Thus, a cured product of the epoxy resin composition comprising the resin has a lower coefficient of moisture absorption and a lower elastic modulus in a high-temperature range higher than a glass-transition temperature (hereinafter, referred to as “Tg”), and exhibits good adhesiveness to a semiconductor chip, an organic substrate and a metal substrate. It also exhibits good fire retardancy and has a feature that it exhibits relatively higher heat resistance with respect to its low crosslinking density.

Examples of the epoxy resin (A) represented by general formula (1) may include phenol-biphenylaralkyl type epoxy resins, but those having the structure of formula (1) may be used without limitations.

The epoxy resin represented by general formula (1) may be combined with another epoxy resin as long as the effects of the former resin are not deteriorated. Examples of an epoxy resin which can be combined include biphenyl type epoxy resins, bisphenol type epoxy resins, stilbene type epoxy resins, phenol novolac type epoxy resins, cresol novolac type epoxy resins, triphenolmethane type epoxy resins, phenolaralkyl type epoxy resins, naphthol type epoxy resins, alkyl-modified triphenolmethane type epoxy resins, triazine-structure containing type epoxy resins and dicyclopentadiene-modified type phenol epoxy resins.

In the light of moisture-resistance reliability as an epoxy resin composition for encapsulating a semiconductor chip, it is preferable that Na and Cl ions as ionic impurities exit as little as possible. In view of curability, an epoxy equivalent may be, for example, 100 g/eq to 500 g/eq both inclusive.

The phenol resin (B) represented by general formula (2) has a hydrophobic phenylene group or hydrophobic and rigid biphenylene structure within a main chain thereof. Thus, a cured product of the epoxy resin composition comprising the resin has a lower coefficient of moisture absorption and a lower elastic modulus in a high-temperature range higher than a Tg, and exhibits good adhesiveness to a semiconductor chip, an organic substrate and a metal substrate. It also exhibits good fire retardancy and has a feature that it exhibits relatively higher heat resistance with respect to its low crosslinking density.

Examples of the phenol resin (B) represented by general formula (2) may include phenol biphenylaralkyl resins and phenolaralkyl resins, but those having the structure of formula (2) may be used without limitations.

In this invention, the phenol resin represented by general formula (2) may be combined with another phenol resin as long as the effects of the former phenol resin are not deteriorated. Examples of a phenol resin which can be combined include phenol novolac resins, cresol novolac resins, triphenolmethane resins, terpene-modified phenol resins, dicyclopentadiene-modified phenol resins and naphtholaralkyl resins (including a phenylene or biphenylene structure). In the light of curability, a hydroxyl equivalent may be, for example, preferably 90 g/eq to 250 g/eq both inclusive.

Examples of an inorganic filler (C) generally include fused silica, spherical silica, crystal silica, alumina, silicon nitride and aluminum nitride, which are commonly used for an encapsulating material. A particle size of the inorganic filler may be 0.01 μm to 150 μm both inclusive in the light of filling properties into a mold.

A filling amount of the inorganic filler (C) may be, for example, 84 wt % to 90 wt % both inclusive of the total amount of an epoxy resin composition. If a filling amount is too low, water absorption by a cured product of the epoxy resin composition may be increased, leading to deterioration in strength and thus insufficient solder resistance. While if it is too high, flowability may be deteriorated, leading to deterioration in moldability.

The curing accelerator (D) may be any compound which can accelerate a reaction between an epoxy group in an epoxy resin and a hydroxyl group in a phenol resin, and may be selected from those commonly used in an epoxy resin composition as an encapsulating material for a semiconductor chip. Specific examples include phosphorous-containing compounds such as organophosphines, tetra-substituted phosphonium compounds and phosphobetaine compounds; and nitrogen-containing compounds such as 1,8-diazabicyclo(5,4,0)undecene-7, benzyldimethylamine and 2-methylimidazole.

Examples of an organophosphine include primary phosphines such as ethylphosphine and phenylphosphine; secondary phosphines such as dimethylphosphine and diphenylphosphine; tertiary phosphines such as trimethylphosphine, triethylphosphine, tributylphosphine, and triphenylphosphine.

A tetra-substituted phosphonium compound may be a compound represented by general formula (3):

wherein P is phosphorous; R₁, R₂, R₃ and R₄ are substituted or unsubstituted aromatic or alkyl; A is an anion of an aromatic organic acid having a functional group selected from hydroxyl, carboxyl and thiol in the aromatic ring; AH is an aromatic organic acid having at least one selected from hydroxyl, carboxyl and thiol in the aromatic ring; a and b are an integer of 1 to 3 both inclusive; and c is an integer of 0 to 3 both inclusive, provided that a=b.

The compound represented by general formula (3) may be prepared as follows. First, a tetra-substituted phosphonium bromide, an aromatic organic acid and a base are combined in an organic solvent and homogeneously mixed to generate aromatic organic acid anions in the solution system. Then, by adding water, the compound represented by general formula (3) may be precipitated.

A preferable compound represented by general formula (3) is a compound wherein R₁, R₂, R₃ and R₄ bound to phosphorous are phenyl; AH is a compound having a hydroxyl group in an aromatic ring, that is, phenols; and A is preferably an anion of the phenols.

A phosphobetaine compound may be a compound represented by general formula (4):

wherein X is hydrogen or alkyl having 1 to 3 carbon atoms both inclusive; Y is hydrogen or hydroxyl; m and n are an integer of 1 to 3 both inclusive.

The compound represented by general formula (4) may be prepared as follows. First, an iodophenol and a triaromatic-substituted phosphine are homogeneously mixed in an organic solvent and by using a nickel catalyst, a product is precipitated as an iodonium salt. The iodonium salt and a base may be homogeneously mixed in an organic solvent and water may be, if necessary, added to precipitate the compound represented by general formula (4).

The compound represented by general formula (4) may be selected from, but not limited to, those wherein X is hydrogen or methyl, and Y is hydrogen or hydroxyl, which may be used alone or in combination of two or more.

An amount of the curing accelerator (D) may be 0.1 wt % to 1 wt % both inclusive, preferably 0.1 wt % to 0.6 wt % both inclusive of the total amount of an epoxy resin composition. If the amount of the curing accelerator (D) is too low, desired level of curability may not be obtained, while if too high, flowability may be deteriorated.

The silane coupling agent (E) may be selected from epoxysilanes, aminosilanes, ureidosilanes and mercaptosilanes. However, it may be, without limitations, any one which can be reacted between an epoxy resin composition and an inorganic filler to improve interface strength between the epoxy resin composition and the inorganic filler.

Compound (F) containing two and more hydroxyl groups combined with each of adjacent carbon atoms comprising an aromatic ring (hereinafter, referred to as “Compound (F)”) significantly improves viscosity and flow properties by synergistic effect with a silane coupling agent (E). The silane coupling agent (E) is essential for adequate effects of Compound (F).

These silane coupling agents (E) may be used alone or in combination of two or more. An amount of the silane coupling agent (E) may be 0.01 wt % to 1 wt % both inclusive, preferably 0.05 wt % to 0.8 wt % both inclusive, more preferably 0.1 wt % to 0.6 wt % both inclusive of the total amount of an epoxy resin composition. If the amount is too low, Compound (F) may not be adequately effective and solder resistance of a semiconductor package may be deteriorated. If too high, an epoxy resin composition becomes so water-absorptive that solder resistance in a semiconductor package may be also deteriorated.

Compound (F) containing two and more hydroxyl groups on adjacent carbon atoms comprising an aromatic ring may contain optionally a substituent other than the hydroxyl groups.

Compound (F) may be a monocyclic compound represented by general formula (5):

wherein one of R₁ and R₅ is hydroxyl and the other is hydrogen, hydroxyl or a substituent other than hydroxyl; and R₂, R₃ and R₄ are hydrogen, hydroxyl or a substituent other than hydroxyl; or a polyclic compound represented by general formula (6):

wherein one of R₁ and R₇ is hydroxyl and the other is hydrogen, hydroxyl or a substituent other than hydroxyl; and R₂, R₃, R₄, R₅ and R₆ are hydrogen, hydroxyl or a substituent other than hydroxyl.

Examples of the monocyclic compound represented by general formula (5) include catechol, pyrogallol, gallic acid, gallic acid esters, and their derivatives. Examples of the polycyclic compound represented by general formula (6) include 1,2-dihydroxynaphthalene, 2,3-dihydroxynaphthalene and their derivatives.

In particular, the above compound preferably has two hydroxyl groups combined with each of adjacent carbon atoms comprising an aromatic ring for flowability and easy control to curability. In the light of volatilization during a kneading process, a core ring may be preferably a naphthalene ring which contributes to lower volatility and weighing stability.

Compound (F) may be, for example, a naphthalene-containing compound such as 1,2-dihydroxynaphthalene, 2,3-dihydroxynaphthalene and their derivatives. Such a compound may be used to further improve controllability in handling an epoxy resin composition and to reduce volatility of the epoxy resin composition.

The compounds as Compound (F) may be used in combination of two or more.

An amount of Compound (F) may be 0.01 wt % to 0.5 wt % both inclusive, preferably 0.02 wt % to 0.3 wt % both inclusive of the total amount of an epoxy resin composition. If the amount is too low, expected viscosity or flow properties by synergetic effect with a silane coupling agent (E) may not be obtained, while if too high, curing of the epoxy resin composition may be inhibited, leading to deteriorated physical properties of a cured product and thus deterioration in its performance as a resin for encapsulating a semiconductor chip.

Although an epoxy resin composition according to this invention comprises the above components (A) to (F) as essential components, it may further contain, if necessary, additives including a fire retardant such as a brominated epoxy resin and antimony trioxide; a mold release; a coloring agent such as carbon black; a low-stress additive such as silicone oil and silicone rubber; and an inorganic ion exchanger as appropriate.

An epoxy resin composition according to this invention may be prepared by homogeneously mixing components (A) to (F) and other additives in a mixer at an ambient temperature, followed by melt-kneading using an appropriate apparatus such as a heating roller, kneader or extruder, cooling and then grinding.

For encapsulating a semiconductor chip using an epoxy resin composition according to this invention to provide a semiconductor device, the composition may be molded and cured by an appropriate molding process such as transfer molding, compression molding and injection molding.

An epoxy resin composition according to this invention may be suitably used for encapsulating a variety of semiconductor chips. It may be used, for example, as an encapsulating resin for a surface mounting type semiconductor device such as QFP (quad flat package) and TSOP (thin small outline package). FIG. 1 is a cross-sectional view illustrating a structural example of a semiconductor device produced using an epoxy resin composition according to this invention. A semiconductor chip 1 is fixed on a die pad 2 via a cured die bonding material 6. Gold wires 3 couple the semiconductor chip 1 to lead frames 4. The semiconductor chip 1 is encapsulated with an encapsulating resin 5.

The semiconductor device shown in FIG. 1 may be prepared by molding and curing the above epoxy resin composition as the encapsulating resin 5 by an appropriate process such as transfer molding, compression molding and injection molding and then encapsulating the semiconductor chip 1.

Since the semiconductor device shown in FIG. 1 is encapsulated by a encapsulating resin composition comprising Compound (F) containing two and more hydroxyl groups combined with each of adjacent carbon atoms comprising an aromatic ring, suitable viscosity and flow properties of the encapsulating resin composition may be achieved. Thus, a semiconductor device with good moldability can be consistently provided.

By encapsulating the semiconductor chip using an epoxy resin composition comprising an epoxy resin represented by general formula (1) and a phenol resin represented by general formula (2), a semiconductor device with further excellent fire retardancy and solder resistance can be more consistently provided.

This invention will be more specifically described with reference to, but not limited to, Examples. Throughout this disclosure, a blending ratio is presented as parts by weight.

EXAMPLE 1

A phenol biphenylaralkyl type epoxy resin (Nippon Kayaku Co., Ltd., NC3000-P, epoxy equivalent: 274, “n” in formula (1) is 2.8 as an average, softening point: 58° C.): 7.35 wt parts;

phenol biphenylaralkyl resin (Meiwa Kasei Co., Ltd., MEH-7851SS, hydroxyl equivalent 203, “n” in formula (2) is 2.5 as an average, softening point: 65° C.): 5.5 wt parts;

-   -   spherical fused silica (average particle size: 30 μm): 86.0 wt         parts; γ-glycidoxypropyl-trimethoxysilane: 0.4 wt parts;     -   triphenyl phosphine: 0.2 wt parts;     -   2,3-dihydroxynaphthalene (Reagent grade): 0.05 wt parts;     -   carnauba wax: 0.2 wt parts; and     -   carbon black: 0.3 wt parts

were mixed in a mixer at an ambient temperature, followed by melt kneading by a heating roller at 80 to 100° C., cooling and then grinding to obtain an epoxy resin composition. The resultant epoxy resin composition was evaluated as follows. The evaluation results are shown in Table 1.

Spiral flow; the epoxy resin composition was molded by a low-pressure transfer molding machine under the conditions of a temperature: 175° C., a molding pressure: 6.9 MPa and a pressure keeping time: 120 sec, using a mold in accordance with EMMI-1-66, and then a spiral flow was determined. A spiral flow is a parameter for flowability. The larger the parameter is, the better flowability is. A unit is “cm”.

Curing torque ratio: Using a curastometer (Orientec Inc., JSR Curastometer Type IVPS), a torque was determined 90 and 300 sec after initiation of heating at a mold temperature of 175° C. and a curing torque ratio=(torque after 90 sec)/(torque after 300 sec) was calculated. A torque determined by a curastometer is a parameter for thermal rigidity. The larger the curing torque ratio is, the better curability is. A unit is “%”.

Solder resistance-reflow cracking: using a low-pressure transfer molding machine, a 100pQFP frame (Cu frame) with a body size of 14×14×1.4 mm to which an Si chip with a size of 6×6×0.30 mm is adhered was molded under the conditions of a mold temperature: 175° C., an injection time: 10 sec, a curing time: 90 sec and an injection pressure: 9.8 MPa. After post-curing at 175° C. for 8 hrs, it was humidified under the condition of 85° C. and 85% for 48 hrs and passed through an IR reflow at a peak temperature of 260° C. consecutive three times (three times, 10 sec at 255° C. or higher for each run). Then, it was examined for internal cracks and delaminations using an ultrasonic test equipment. Evaluation was based on the numbers of delaminations between the chip and the encapsulating resin and internal cracks in 10 packages.

Fire retardancy: using a low-pressure transfer molding machine, test pieces for fire retardancy with a thickness of 3.2 mm were prepared under the conditions of a mold temperature: 175° C., an injection time: 15 sec, a curing time: 120 sec, and an injection pressure: 9.8 MPa and was tested for fire retardancy in accordance with the specification of UL94.

EXAMPLES 2 TO 13 AND COMPARATIVE EXAMPLES 1 TO 11

According to the blending ratios shown in Tables 1 and 2, epoxy resin compositions were prepared and evaluated as described in Example 1. The evaluation results are shown in Tables 1 and 2.

Components used other than those in Example 1 are as follows.

A biphenyl type epoxy resin (Japan Epoxy Resin Inc., YX4000H, epoxy equivalent: 195, melting point: 105° C.);

phenolaralkyl resin (Mitsui Chemical Inc., XLC-LL, hydroxyl equivalent: 174, “n” in formula (2) is 3.6 as an average, softening point: 79° C.);

a cresol novolac type epoxy resin (Nippon Kayaku Co., Ltd., EOCN 1020-55, epoxy equivalent: 198, softening point: 55° C.);

phenol novolac resin (hydroxyl equivalent: 104, softening point: 80° C.);

γ-mercaptopropyltrimethoxysilane;

1,8-diazabicyclo(5,4,0)undecene-7 (hereinafter, referred to as “DBU”);

a curing accelerator represented by formula (7);

a curing accelerator represented by formula (8);

1,2-dihydroxynaphthalene (Reagent grade);

catechol (Reagent grade);

pyrogallol (Reagent grade);

1,6-dihydroxynaphthalene (Reagent grade); and

resorcinol (Reagent grade).

TABLE 1 Example 1 2 3 4 5 6 7 8 9 10 11 Phenol biphenylaralkyl type epoxy resin 7.35 4.0 8.65 7.5 7.13 7.42 7.35 7.35 7.35 7.35 7.35 Biphenyl type epoxy resin 1.0 Phenol biphenylaralkyl resin 5.5 2.5 5.5 5.5 5.3 5.5 5.5 5.5 5.5 5.45 5.45 Phenolaralkyl resin 1.3 Spherical fused silica 86.0 90.0 84.5 86.0 86.0 86.0 86.0 86.0 86.0 86.0 86.0 γ-Glycidoxypropyltrimethoxysilane 0.4 0.5 0.3 0.05 0.85 0.03 0.4 0.4 0.4 0.4 γ-Mercaptopropyltrimethoxysilane 0.4 Triphenylphosphine 0.2 0.13 0.25 0.2 0.2 0.2 0.2 0.2 DBU 0.2 Curing accelerator of formula (7) 0.25 Curing accelerator of formula (8) 0.25 2,3-Dihydroxynaphthalene 0.05 0.07 0.1 0.25 0.02 0.35 0.05 0.05 0.05 0.05 1,2-Dihydroxynaphthalene 0.05 Catechol Pyrogallol 1,6-Dihydroxynaphthalene Resorcinol Carnauba wax 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Carban black 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 Spiral flow (cm) 100 85 121 115 96 118 104 106 102 112 105 Curing torque (%) 65 61 66 60 68 58 63 63 61 85 89 ratio Solder resistance- Chip delamination 0 0 0 0 0 0 0 0 0 0 0 cracking Internal crack 0 0 0 0 0 0 0 0 0 0 0 Fire retardancy V-0 V-0 V-0 V-0 V-0 V-0 V-0 V-0 V-0 V-0 V-0

TABLE 2 Comparative Example 1 2 3 4 5 6 7 8 9 10 11 Phenol biphenylaralkyl type epoxy resin 7.4 9.4 7.4 7.5 7.6 7.35 7.35 7.4 7.35 7.35 Biphenyl type epoxy resin Cresol novolac type epoxy resin 6.9 Phenol biphenylaralkyl resin 5.5 5.5 5.52 5.65 5.5 5.5 5.5 5.5 5.5 Phenolaralkyl resin 6.0 Phenol novolac resin 3.5 Spherical fused silica 86.0 86.0 86.0 86.0 86.0 86.0 86.0 86.0 86.0 86.0 86.0 γ-glycidoxypropyltrimethoxysilane 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 γ-Mercaptopropyltrimethoxysilane 0.4 Triphenylphosphine 0.2 0.15 0.15 0.2 0.06 0.2 0.2 0.2 DBU 0.2 Curing accelerator of formula C7) 0.25 Curing accelerator of formula C8) 0.25 2,3-Dihydraxynaphthalens 0.05 0.05 0.05 1,2-Dihydroxynaphthalene Catechol Pyrogallol 1,6-Dihydroxynaphthalene 0.05 Resorcinol 0.05 Carnauba wax 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 Carbon black 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 0.3 Spiral flow (cm) 80 76 71 62 114 76 78 81 68 89 77 Curing torque (%) 65 67 70 62 7 56 65 54 57 85 89 ratio Solder resistance- Chip delamination 4 2 chip 3 9 5 4 4 2 3 cracking Internal crack 0 10 exposure 0 Poor 0 0 0 0 0 0 Fire retardancy V-0 V-1 HB V-0 Releasing V-0 V-0 V-0 V-0 V-0 V-0 

1. A resin composition for encapsulating a semiconductor chip comprising: an epoxy resin (A) represented by general formula (1):

wherein R represents hydrogen or alkyl having up to four carbon atoms; and n is a positive number from 0.5 to 5 as an average; a phenol resin (B) represented by general formula (2):

wherein R₁ represents phenylene or biphenylene; R₂ represents hydrogen or alkyl having up to four carbon atoms; and n is a positive number from 0.5 to 5 as an average; an inorganic filler (C); a curing accelerator (D); a silane coupling agent (E); and Compound (F) containing two and more hydroxyl groups on adjacent carbon atoms in naphthalene ring.
 2. The resin composition for encapsulating a semiconductor chip according to claim 1, wherein the resin composition comprises said Compound (F) in more than or equal to 0.01 wt %.
 3. The resin composition for encapsulating a semiconductor chip according to claim 1, wherein the resin composition comprises said silane coupling agent (E) in 0.01 wt % to 1 wt % both inclusive.
 4. The resin composition for encapsulating a semiconductor chip according to claim 1, wherein said Compound (F) contains two hydroxyl groups on adjacent carbon atoms in said naphthalene ring.
 5. The resin composition for encapsulating a semiconductor chip according to claims 1, wherein the resin composition comprises said inorganic filler (C) in 84 wt % to 90 wt % both inclusive.
 6. A semiconductor device wherein a semiconductor chip is encapsulated by the resin composition according to claim
 1. 7. The resin composition for encapsulating a semiconductor chip according to claim 1, wherein said inorganic filler (C) is present in an amount of 84 wt % to 90 wt % both inclusive, said silane coupling agent (E) is present in an amount of 0.01 wt % to 1 wt % both inclusive, and said Compound (F) is present in an amount of 0.01 wt % to 0.5 wt % both inclusive.
 8. The resin composition for encapsulating a semiconductor chip according to claim 1, wherein said curing accelerator is a compound represented by general formula (3) or (4);

wherein P is phosphorous; R₁, R₂, R₃ and R₄ are substituted or unsubstituted aromatic or alkyl; A is an anion of an aromatic organic acid having a function group selected from the group consisting of hydroxyl, carboxyl and thiol in the aromatic ring; AH is an aromatic organic acid having at least one selected from hydroxyl, carboxyl and thiol in the aromatic ring; a and b are an integer of 1 to 3 both inclusive; and c is an integer of 0 to 3 both inclusive, provided that a=b;

wherein X is hydrogen or alkyl having 1 to 3 carbon atoms both inclusive; Y is hydrogen or hydroxyl; m and n are an integer of 1 to 3 both inclusive. 